不同调理剂对镉铅污染红壤的修复效果

Effects of Different Conditioners on Remediation of Cadmium and Lead Contaminated Acidic Red Soil

  • 摘要:
    目的 针对红壤pH值低、结构性差及镉、铅复合污染等问题,探讨不同调理剂对镉、铅污染红壤的修复与改良效果,以期为红壤地区镉铅污染土壤的治理提供科学依据。
    方法 采集三明尤溪梅县镇严格管控区农田红壤,设置未添加调理剂(CK,对照)、添加猪粪有机肥(T1)、添加牡蛎壳粉(T2)、添加炭化牡蛎壳(T3)、添加大豆秸秆炭(T4)和添加牡蛎壳改性大豆秸秆炭(T5)6个处理,等比例添加调理剂,进行室内培养,再采集盆中土壤、测定土壤相关指标,研究不同调理剂修复镉铅重金属污染、改良土壤的效果。
    结果 施用土壤调理剂可以不同程度地提升土壤pH,较对照提高0.45 ~ 1.66个单位,其中T2、T3、T4和T5处理土壤pH与对照相比有显著差异;②不同调理剂施用使土壤持水性、阳离子交换量、电导率、土壤机械稳定性团聚体(5 ~ 2 mm、1 ~ 0.25 mm和< 0.25 mm)、有机碳、全氮、全钾和速效养分含量增加,土壤容重降低,而土壤全磷含量和土壤水稳定性团聚体含量无显著差异;③各处理土壤有效态镉、铅含量相比对照分别下降了17.62% ~ 32.46%和14.26% ~ 35.43%,其中T3、T5下降幅度最大。④不同调理剂施入土壤后,土壤中镉以碳酸盐结合态与铁锰氧化物结合态两种形态为主,其占有效镉含量的55.95% ~ 74.09%;其次以交换态和残渣态存在,占比分别为15.36% ~ 30.92%和2.81% ~ 12.43%。铅的赋存形态以铁锰氧化物结合态为主,分布比例为56.16% ~ 62.50%,其次是移动性弱的残渣态,占比为21.19% ~ 28.76%。施用土壤调理剂可促使镉、铅的交换态向活性更弱的碳酸盐结合态与铁锰氧化物结合态转化。
    结论 从土壤肥力提升效果、镉铅污染修复能力和酸性改良程度等方面考虑,猪粪有机肥和牡蛎壳改性大豆秸秆炭更适合农田土壤修复。

     

    Abstract:
    Objective In response to the issues of low pH, poor structure, and combined pollution of cadmium (Cd) and lead(Pb)in red soil, this study investigated the remediation and amendment effects of various conditioning agents on Cd and Pb contaminated red soil, with the aim of providing a scientific basis for the management of Cd and Pb polluted soils in red soil regions.
    Method Soil samples were collected from the strictly controlled area of Youxi Meixian Town in Sanming to conduct a pot experiment. A total of six treatments were set up, including a control group (CK) without any amendment and five amendment treatments: T1 (organic fertilizers of pig manure), T2 (oyster shells powder), T3 (calcined oyster shells), T4 (soybean straw charcoal), and T5 (soybean straw biochar modified by oyster shells). The amendments were incorporated into the soil samples at equal proportions, followed by indoor incubation. After the incubation period, soil samples were collected from the pots for analysis of various soil properties.
    Result ①The utilization of soil conditioners markedly elevated the soil pH, exhibiting a rise of 0.45 - 1.66 units relative to the control group. Notably, treatments T2, T3, T4 and T5 demonstrate a more pronounced enhancement in soil pH levels. ②Different soil conditioners can enhance soil water retention, cation exchange capacity, electrical conductivity, soil mechanical stability aggregate (5 - 2 mm, 1 - 0.25 mm and < 0.25 mm), as well as the content of organic carbon, total nitrogen, total potassium, and available nutrient content to a certain extent, reduce soil bulk density, and have minimal impact on the total phosphorus content and soil water stability aggregate of the soil. ④After the application of different soil conditioners, Cd in the soil primarily exists in the forms of carbonate-bound and Fe-Mn oxide-bound fractions, constituting 55.95% - 74.09% of the total Cd content. This is followed by the exchangeable fraction, ranging from 15.36% - 30.92%, and the residual fraction, which varied between 2.81% and 12.43% of the total Cd content. The predominant speciation of Pb was the Fe-Mn oxide-bound form, with a distribution range of 56.16% - 62.50%, followed by the less mobile residual form, which constitutes 21.19% - 28.76%. The application of soil conditioners can promote the transformation of Cd and Pb from the exchangeable fraction to the carbonate-bound and Fe-Mn oxide-bound fraction.
    Conclusion Evaluation of soil fertility enhancement, Cd and Pb pollution remediation capacity, and acidic soil amelioration indicated that T1 (organic fertilizer of pig manure) and T5 (soybean straw biochar modified by oyster shells) were more appropriate for the remediation of agricultural soils.

     

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